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Under UV irradiation, the trans-cis isomerization of the azobenzene ligands causes the shrinkage of the exible gel network because of the shorter molecular length of the cis conformation than the trans conformation, which bends the silicon substrate upwardly and generates a tensile stress on the substrate At the photostationary state, the ratio between the two isomers (trans:cis) reaches a maximum, thus the stress stays at the maximum level When the UV light is switched off, the thermal cis-trans isomerization of the azobenzene moieties relieves the tensile stressRelated: Barcode Generation Excel Library, Creating Barcode Excel , Print Barcode Crystal Library.

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Photochemical and thermal isomerization in polymer matrixes zo compounds in polystyrene J Polym Sci, Part A 9(11):3161 3168 Ramanujam PS, et al 2001 Physics and technology of optical storage in polymer thin lms Synth Met 124(1):145 150 Rau H 1968 Radiationless deactivation of azo compounds and light fastness of azo dyes Berichte der Bunsen Gesellschaft 72(3):408 414 Rau H 1990 Photoisomerization of Azobenzenes In: Rebek J, editor Photochemistry and Photophysics Boca Raton (FL): CRC Press, p 119 141 Rau H, Lueddecke E 1982 On the rotation inversion controversy on photoisomerization of azobenzenes Experimental proof of inversion J Am Chem Soc 104(6):1616 1620 Rau H, Roettger D 1994 Photochromic azobenzenes which are stable in the trans and cis forms Mol Cryst Liq Cryst Sci Technol, A 246:143 146 Rau H, Crosby AD, Schau er A, Frank R 1981 Triplet sensitized photoreaction of azobenzene in sulfuric acid.

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Z Naturforsch, A: Phys Sci 36(11):1180 1186 Rau H, Greiner G, Gauglitz G, Meier H 1990 Photochemical quantum yields in the A B system when only the spectrum of A is known J Phys Chem 94(17):6523 6524 Razna J, Hodge P, West D, Kucharski S 1999 NLO properties of polymeric Langmuir Blodgett lms of sulfonamide substituted azobenzenes J Mater Chem 9(8):1693 1698 Reynier N, Dozol J F, Saadioui M, Asfari Z, Vicens J 1998 Complexation properties of a new photosensitive calix[4]arene crown ether containing azo unit in the lower rim towards alkali cations Tetrahedron Lett 39(36):6461 6464 Richert L, et al 2002 Cell interactions with polyelectrolyte multilayer lms Biomacro molecules 3(6):1170 1178 Rmaile HH, Schlenoff JB 2003 Optically active polyelectrolyte multilayers as membranes for chiral separations J Am Chem Soc 125(22):6602 6603 Rochon P, Batalla E, Natansohn A 1995 Optically induced surface gratings on azoaro matic polymer lms.

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Appl Phys Lett 66(2):136 138 Rottger D, Rau H 1996 Photochemistry of azobenzenophanes with three membered bridges J Photochem Photobiol A Chem 101(2 3):205 214 Rouse JH, Ferguson GS 2002 Stepwise incorporation of nonpolar polymers within polyelectrolyte multilayers Langmuir 18(20):7635 7640 international standard book number encoder touse isbn Pdf417 2d Barcode implementation for net c# Related: ASPNET C# Barcode Generating , NET Barcode Generation , Barcode Generating SSRS how to.

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Using Barcode Control SDK for Java Control to generate, create, read, scan barcode image in ava applications In principle, elastomers can undergo larger thermal expansion because of polymer chain exibility Such a grating might be used as a sensor for the detection of abrupt temperature change, since a large thermal expansion can cause changes in index modulation and grating period In the case of electrically switchable gratings, LCs remain the material of choice because of the ease of molecular reorientation under the effect of a voltage The photoisomerization of azobenzene should play the role of trigger for the grating formation Self-assembled LC gels combine the property of electric eld orientation of LCs and the possibility of a structural rearrangement induced by the photoisomerization of the azobenzene gelator Even though the grating obtained from the cholesteric LC gel as described in Section 11.

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4 falls short for practical applications, the interest of exploiting self-assembled LC gels is clear, since this approach may be generalized for many systems made from designed gelators and various types of LCs The key to the grating formation process in self-assembled LC gels is the dissolution of the physical network in the LC host in irradiated areas This may be enhanced by using azobenzene gelators whose cis form has a signi cantly higher polarity than the trans form, which increases the surface tension of the brous aggregates It also helps if the gelator could form very thin nano brous aggregates giving rise to a large speci c surface and thus a signi cant number of gelator molecules on the surface undergoing the trans cis photoisomerization Finally, further research effort is worth being made on materials for recording optically switchable diffraction gratings.

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