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In a steady-state batch liquid vessel, dCA /dt and QL are zero and the mass transfer rate equals the reaction rate All other cases are more complicated First consider the terms making up the mass transfer rate kL The rst term is the overall mass transfer coef cient kL This is the reciprocal of the mass transfer resistance This development is based on the lm theory concept of mass transfer and consists of resistances in series: the resistance of the gas lm (usually negligible), the resistance of the liquid lm (the most important), and the resistance of any contaminant layer between the phases, such as solids or a surfactant Again for simplicity we assume that all resistance is in the liquid phase The variable kL is most dependent on the chemistry of the uids.

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It can be estimated from surface renewal theory and related to molecular diffusivity and dispersed phase bubble or drop or particle size In addition, the liquid lm coef cient can be increased due to rapid reactions which effectively thin the diffusion layer This is discussed below kL estimates are often not reliable and are usually obtained by experiment in well-understood geometries a This is the area per unit volume of a bubble Actually, it is an average of the total surface area over the total bubble volume Thus, it can be written as 6/d, where d is the average bubble or drop or particle size In 11 there are several correlations for this value based on a large variety of experiments The average drop size is the result of the combination of drop or bubble breakup and coalescence.

Breakup is determined by uid forces and the surface or interfacial tension-resisting force Coalescence is controlled by various physiochemical effects, such as double layers and the presence of surface-active agents For example, coalescing systems such as air and water will have a certain bubble size under a given set of agitation conditions The addition of small amounts of salt will decrease coalescence and make smaller drops, giving larger holdups and increased mass transfer Addition of surfactants will also reduce bubble size and increase holdup,.

For example, following venting in a two-stage extruder, the adiabatic temperature rise accompanying generation of a 1450 psi (100 bar) discharge pressure would be about an additional 50 C. The Kokneader (Figure 16-25) is a special single-screw extruder with interrupted ights on the screw and mixing teeth projecting inward from the barrel wall. The screw reciprocates as well as rotates. Passage of the teeth through the channels creates multiple mixing actions, as described by Case (1998), as well as preventing adherence of the mixture within the screw channel.

For Windows 98SE, Windows 2000, Windows NT4 (with SP 6 or later), Windows Me, or Windows XP: PC with a Pentium II processor running at 300 Mhz or faster At least 96 MB of total RAM installed on your computer; for best performance, we recommend at least 128 MB Ethernet network interface card (NIC) or modem with a speed of at least 28,800 bps A CD-ROM drive For Macintosh: A G3 or faster processor running OS 9.1 or later, or OS X 10.1 or later At least 96 MB of total RAM installed on your computer; for best performance, we recommend at least 128 MB

Notice that the table is instantly positioned to the right, and the following paragraph flows to the left. Now position the bottom table in the center without wrapping. 1. Select the bottom table. 2. From the Layout category of the Insert bar, choose Insert Div Tag. The necessary CSS rules (discussed earlier in the Centering a Table in CSS ) are already in the attached CSS style sheet. 3. When the Insert Div Tag dialog box opens, leave the Insert list entry set to Wrap Around Selection. 4. Choose centerDiv from the Class list and click OK when you re done. continued

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