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Remember this line from the section What is a relational database earlier in this chapter: A place for everything, and everything in its place The process of making a place for everything in your database is called normalization, and it is probably the single most important aspect of database design. Put another way, normalization is the process of structuring data to fit the formal definition of a relational database. The layered approach that we recommend that you use to design your databases helps you create inherently normalized database models from the very beginning, but you often inherit a database with a very bad data structure. This section gives you the basics of how to normalize a bad database structure into a good one. You begin with a very bad design that places everything into one big entity, as shown in Figure 8-18. The example here is a database that tracks puppies and the tricks that they can perform.

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Press, Cambridge, 1984. Delahay, P., New Instrumental Methods in Electrochemistry, Interscience, New York, 1954. Geddes, A. L., and R. B. Pontius, Determination of diffusivity, in Technique of Organic Chemistry (Ed. A. Weissberger), Vol. 1, Part 2, 3rd ed., Interscience, New York, 1960, p. 895. Marchiano, S. L., and A. J. Arvia, Diffusion in absence of convection. Steady state and nonsteady state, CTE, 6, 65 (1983).

Puppy PuppyNumber PuppyName KennelCode KennelName KennelLocation TrickID_1 TrickName_1 TrickWhereLearned_1 SkillLevel_1 TrickID_2 TrickName_2 TrickWhereLearned_2 SkillLevel_2 TrickID_n TrickName_n TrickWhereLearned_n SkillLevel_n

This entity originally contains enough columns to store 40 puppy tricks (abbreviated so we can fit it on the page!)

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Morf, W. E., The Principles of Ion-Selective Electrodes and of Membrane Transport,

Figure 8-18: The badly mistaken idea that one entity fits all. Your first clue that the database shouldn t be structured as a single entity is that huge section of repeating attributes (TrickName_1, TrickName_2, etc.), but how do you go about normalizing it You normalize a database by modifying it through increasing degrees of normalization known as normal forms.

First Normal Form (1NF)

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To achieve First Normal Form, you must eliminate all repeating groups of attributes from your entities, as shown in Figure 8-19. A repeating group of attributes is fairly easy to spot, such as the group of TrickID_N, TrickName_N, TrickWhereLearned_N, and SkillLevel_N, where N

Akademiai Kiado, Budapest, and Elsevier, Amsterdam, 1981. Newman, J., Electrochemical Systems, Prentice-Hall, Englewood Cliffs, 1973. Overbeek, J. Th. G., The Donnan equilibrium, in Progress in Biophysics and Biophysical Chemistry, Vol. 6, Pergamon Press, London 1956.

goes from 1 to 40. When you build all those repeating groups into a single entity, you invariably leave one or more of them empty, which not only requires that you leave most or all of their attributes nullable but also leaves a lot of empty space in the physical tables produced from your design. Both of these practices constitute bad database design.

Figure 8-19: The original entity normalized to First Normal Form (1NF). You move this repeating group into an entity of its own so that you can have as many or as few of these groups as you need, and you don t have to make any columns nullable. Now your database is said to be in First Normal Form, or 1NF.

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2.6 The Mechanism of Ion Transport in Solutions, Solids, Melts and Polymers Diffusion is one of the most important natural processes. The varying rate of diffusion yields an excellent characteristic of individual states of aggregation. While diffusion coefficients in gases are of the order of 10"1 cm2 s~\ those in solutions are of the order of 10~ 5 cm 2 -s~ 1 and, in solids, of The mobility of a species w, is a parameter connecting diffusion and migration processes. This section will be concerned primarily with the qualitative theory of mobility, which has characteristic properties for

Second Normal Form (2NF)

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