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of thermal conductivity is more than offset by the price of the substrate and the ability to have chip geometry moulded onto it For SiN substrates, the cost of the substrate is prohibitive, and the ability to have chip breaker moulds makes them unattractive Unlike PCDs, coated diamonds are thin and conform to the chip geometry on the carbide substrate, which is a major advantage [38] By using chemical vapour deposition (CVD) techniques, diamond can be deposited over large areas The earliest method of producing diamonds at a reasonable deposition rate was developed in the Soviet Union Figure 232 shows the schematic diagram of the experimental apparatus The method is based on the transport of carbon from a graphite secretor to the substrate by means of a hydrogen catalyst The graphite was heated Fig 232: A schematic diagram for diamond deposition [38] by optically to a temperature of about 2,000 C A fraction of the hydrogen gas in contact with the graphite was converted to atomic hydrogen, which etched the graphite, resulting in a number of hydrocarbon gas species such as methane and acetylene The hydrocarbons diffused to the cooler substrate held at about 1,000 C, where it reacted to deposit diamond [39] For a better understanding, three CVD methods for diamond deposition are briefly described Thermal CVD (Hot filament, TF CVD) The hot filament method was the first practical method to produce diamond in a systematic way because it had a greater degree of process control Figure 233 (a) shows a schematic diagram of a hot filament reactor at NIST A hydrogen and methane feed gas mixture is allowed to pass over a hot filament The quality of a diamond produced improves with decreasing methane fractions in the feed gas The plasma is generated by a hot filament (W, Ta, Re) heated to 2,000 C or higher, around which hydrogen is dissociated into highly reactive atomic hydrogen, and hydrocarbon compounds are stripped from a hydrogen-forming radical In the simplest case, that of methane, CH4, a methyl radical, CH3, or probably an HC radical is formed The substrate is at a distance of between 5 and 20 mm from the heated filament, and its temperature is between 700 and 1,000 C The gas consumption is typically H2:CH4 = 99:1 Under these conditions, the growth rate is of the order of 1 m/h Figure 233 (b) illustrates a hot filament CVD reactor In this method, a small amount of the filament evaporation occurs and contaminates the growing diamond film This metallic contamination is not too much of a constraint for coatings used in mechanical applications of such as tools or general wear parts [40] However, it is a nuisance when envisaging electronic applications such as active components as well as optical sensor devices.

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the distances to the centromere, in map units, for each locus are for locus a: (1 2) 9 150 1 1,000 8 100

Compute the rms value of the sinusoidal current i(t) = I cos( t)

Known Quantities: Functional form of the periodic signal i(t) Find: Rms value of i(t) Analysis: Applying the de nition of rms value in equation 424, we compute:

8.4 centimorgans for locus b: (1 2) 101 150 1 1,000 8 100

2 /

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